Microsoft has released two sites with tons of free training. Yup, I checked it out and it's free.
"Ramp Up", http://msdn.microsoft.com/en-us/rampup/default.aspx, covers topics from moving from ASP or PHP to ASP.NET, ASP.NET, Mobile Developent and Sharepoint.
www.msdev.com has tons of webcasts and training materials, geared towards solution providers, however the content is available for all.
Check it out.
James